A Brief Overview of the General Characteristics and Reactivity Towards Dioxygen of the Ferrous Tris (2-Pyridylmethyl Amine) Series Complexes is Presented
Nasser Thallaj
Prof. Dr. Nasser Thallaj, Professor, Department of Pharmaceutical Chemistry and Drug Quality Control, Faculty of Pharmacy, Al-Rachid Privet University, Damascus, Syria.
Manuscript received on 24 February 2023 | Revised Manuscript received on 01 March 2023 | Manuscript Accepted on 15 April 2023 | Manuscript published on 30 April 2023 | PP: 1-10 | Volume-3 Issue-3, April 2023 | Retrieval Number: 100.1/ijapsr.C4012043323 | DOI: 10.54105/ijapsr.C4012.043323
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Abstract: This paper examines the coordination chemistry of iron to TPA-like nitrogenous tripod ligands, focusing on how the spin state of the metal is affected by the presence of steric constraints and the coordination of acetonitrile ligands which can be displaced easily. Additionally, the reactivity of the derivatives with molecular oxygen, the conservation of geometry between the solid state and the solution and the various coordination geometries, electronic properties, and redox properties of ferrous tris (2-pyridylmethyl amine) series complexes are discussed. Furthermore, the molecular mechanisms of reactivity of these complexes are evaluated, providing an outlook for future research.
Keywords: Ferrous Tris (2-pyridylmethyl amine) series Coordination chemistry Ligand field theory Redox properties Electron transfer O2 reactivity Oxidation-reduction reaction Catalytic activity Kinetic studies Dioxygen binding
Scope of the Article: Medicinal Chemistry